Pdf the production of synthesis gas by steam reforming. Carbon monoxide from the reforming reaction interacts with water again to produce more hydrogen and carbon dioxide. Steam reforming of methane, ethane, propane, butane, and natural gas over a rhodiumbased catalyst article in catalysis today 14212. History of synthesis gas in 1780, felice fontana discovered that combustible gas. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons. This is achieved in a reformer which reacts steam at high temperature and pressure with methane in the presence of a nickel catalyst. Methane steam reforming methane steam reforming is a chemical process to produce hydrogen and synthesis gas mixture by combination of steam and methane in a reformer at appropriate temperature and pressure in presence of suitable metalbased catalysts 4. The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. Scribd is the worlds largest social reading and publishing site. The superheated steam is mixed with natural gas in the reforming reaction, producing hydrogen gas and carbon monoxide. Steam reforming of methane, ethane, propane, butane, and.
Surface reaction kinetics of steam and co2 reforming as well as oxidation of methane over nickelbased catalysts article pdf available in catalysts 52. Steam reforming or steam methane reforming is a chemical synthesis for producing syngas hydrogen and carbon monoxide from hydrocarbons such as natural gas. It is reversible and strongly endothermic, and according to the principle of le chatelier it must be carried out at high. Pdf in order to produce valuable syngas, industrial processes of dry reforming of methane and steam reforming of methane must be further developed find.
Kinetics, catalysis and mechanism of methane steam reforming. Steam methane reforming is the most common and economical way to make hydrogen. Methane steam reforming reaction behaviour in a packed bed. Methane steam reforming an overview sciencedirect topics. In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. Pdf steam reforming of methane mixtures with ethylene 1. Pdf steam reforming of methane mixtures with ethylene over an. Hydrogen production from catalytic steam reforming of methane. In order to achieve near equilibrium conversion, steam reforming in conventional technology is conducted on a supported nickel catalyst in a multitubular reactor operated at a temperature of 850c, a pressure ranging from 1.
Steam methane reforming process first, water must be heated in a furnace to produce steam. In order to produce valuable syngas, industrial processes of dry reforming of methane and steam reforming of methane must be further developed. The main reaction that pro duces syngas is the steam methane reforming smr process. Steam and dry reforming processes coupled with partial oxidation.